Volume 40 Issue 4
Aug.  2020
Turn off MathJax
Article Contents
Article Navigation >  Journal of Aeronautical Materials  > 2020  >  40(4): 9-18
Qiaosi ZHU, Jiongli LI, Jianqiang GUO, Xuerui LI, Jiafeng LIANG, Yue LI, Xudong WANG. Effect of physical and chemical parameters of graphene on friction and wear properties of PTFE filled with low content graphene[J]. Journal of Aeronautical Materials, 2020, 40(4): 9-18. doi: 10.11868/j.issn.1005-5053.2020.000098
Citation: Qiaosi ZHU, Jiongli LI, Jianqiang GUO, Xuerui LI, Jiafeng LIANG, Yue LI, Xudong WANG. Effect of physical and chemical parameters of graphene on friction and wear properties of PTFE filled with low content graphene[J]. Journal of Aeronautical Materials, 2020, 40(4): 9-18. 10.11868/j.issn.1005-5053.2020.000098
shu

Effect of physical and chemical parameters of graphene on friction and wear properties of PTFE filled with low content graphene

doi: 10.11868/j.issn.1005-5053.2020.000098
  • 1.

    AECC Beijing Institute of Aeronautical Materials，Beijing 100095，China

  • 2.

    Beijing Institute of Graphene Technology，Beijing 100094，China

  • Received Date: 2020-05-28
  • Rev Recd Date: 2020-06-12
    • Available Online: 2020-07-27
  • Publish Date: 2020-08-01
    Abstract
  • 4 types of graphene were used to fabricate graphene/polytetrafluoroethylene (PTFE) composites with loadings of 0.5% and 1% respectively. The average size, thickness, specific surface area and carbon/oxygen ratio (C/O ratio) of these graphene were characterized by SEM, AFM, BET and XPS. The friction coefficient was performed on the Controllable Environment Friction and Wear Instrument. The volume wear rate was carried out with the 3D White Light Interferometer. The results show that at the same load, the C/O ratio of graphene is the main factor affecting the friction coefficient of the composites, while the specific surface area of graphene is the main factor affecting the volume wear rate of the composites. With the addition of 1%（mass fraction, the same below） graphene in PTFE, the friction coefficient is reduced by 27.97% when the C/O ratio reaches 45.64 and the carbon content reaches 97.66%. With a specific surface area reaches 466.78 m2/g, graphene can reduce the volume wear rate of the PTFE composite by 76.46%.

     

    • FullText(HTML)
  • loading
    • References(30)
  • [1] 见雪珍. 填充聚四氟乙烯复合材料的力学性能和摩擦磨损性能研究[D]. 上海: 上海交通大学, 2013.

    JIAN X Z. The study on mechanical properties and friction and wear properties of filled PTFE composites[D]. Shanghai: Shanghai Jiao Tong University, 2013.
    [2] 谢文谦. 石墨烯改性聚四氟乙烯复合材料制备及性能研究[D]. 上海: 华东理工大学, 2016.

    XIE W Q. The preparation of graphene/PTFE composites and performance research[D]. Shanghai: East China University of Science and Technology, 2016.
    [3] KANDANUR S S,RAFIEE M A,YAVARI F,et al. Suppression of wear in graphene polymer composites[J]. Carbon,2012,50:3178-3183. doi: 10.1016/j.carbon.2011.10.038
    [4] BHARGAVA S,KORATKAR N,BLANCHET T A. Effect of platelet thickness on wear of graphene-polytetrafluoroethylene(PTFE)composites[J]. Tribology Letters,2015,59(17):1-12.
    [5] 蒲吉斌,王立平,薛群基. 石墨烯摩擦学及石墨烯基复合润滑材料的研究进展[J]. 摩擦学学报,2014,34(1):93-111.

    PU J B,WANG L P,XUE Q J. Progress of tribology of graphene and graphene-based composite lubricating materials[J]. Tribology,2014,34(1):93-111.)
    [6] 刘虎. 石墨烯对聚四氟乙烯导热和摩擦磨损性能的影响[J]. 工程塑料应用,2017,45(11):123-126. doi: 10.3969/j.issn.1001-3539.2017.11.024

    LIU H. Effects of graphene on thermal conductivity,friction and wear properties of PTFE[J]. Engineering Plastics Application,2017,45(11):123-126.) doi: 10.3969/j.issn.1001-3539.2017.11.024
    [7] 殷向,叶鹏鹏,吴健,等. 改性剂对石墨烯填充碳纤维/PTFE 摩擦磨损性能的影响规律研究[J]. 中国科技论文,2018,13(6):631-635,654. doi: 10.3969/j.issn.2095-2783.2018.06.005

    YIN X,YE P P,WU J,et al. Friction and wear properties of CF/PTFE composites filled with modified graphene[J]. China Sciencepaper,2018,13(6):631-635,654.) doi: 10.3969/j.issn.2095-2783.2018.06.005
    [8] 谢苏江,谢文谦. 石墨烯/聚四氟乙烯复合密封材料的制备及性能研究[J]. 润滑与密封,2018,43(9):104-107. doi: 10.3969/j.issn.0254-0150.2018.09.018

    XIE S J,XIE W Q. The preparation and performance study of graphene/PTFE composites sealing materials[J]. Lubrication Engineering,2018,43(9):104-107.) doi: 10.3969/j.issn.0254-0150.2018.09.018
    [9] JIANG B,PENG B,ZHU A P,et al. Eco-friendly synthesis of graphene nanoplatelets via a carbonation route and its reinforcement for polytetrafluoroethylene composites[J]. Journal of Materials Science,2018,53(1):626-636. doi: 10.1007/s10853-017-1526-3
    [10] ROOYEN L J,BISSETT H,KHOATHANE M C,et al. Preparation of PTFE/graphene nanocomposites by compression moulding and free sintering:a guideline[J]. Journal of Applied Polymer Science,2016,13(17):1-9.
    [11] 王英章. 石墨烯纳米片/聚四氟乙烯复合材料的制备及磨损性能研究[J]. 功能材料,2019,50(6):06116-06119.

    WANG Y Z. Study on the preparation and wear behavior of graphene nanosheet/PTFE composites[J]. Jorunal of Functional Materials,2019,50(6):06116-06119.)
    [12] 雷芸,徐骏,李容,等. 微晶氧化石墨的制备及性能研究[J]. 矿冶工程,2014,34(1):97-99. doi: 10.3969/j.issn.0253-6099.2014.01.026

    LEI Y,XU J,LI R,et al. Study on preparation and performance of microcrystalline graphite oxide[J]. Mining and Metallurgical Engineering,2014,34(1):97-99.) doi: 10.3969/j.issn.0253-6099.2014.01.026
    [13] 万轶,熊党生,李建亮,等. 氧化还原法制备石墨烯对镍基复合镀层的摩擦学性能影响[J]. 腐蚀科学与防护技术,2019,31(3):297-302. doi: 10.11903/1002.6495.2018.156

    WAN Y,XIONG D S,LI J L,et al. Tribological properties of Ni-based composite coating with graphene prepared by oxidation- and reduction-method[J]. Corrosion Science and Protection Technology,2019,31(3):297-302.) doi: 10.11903/1002.6495.2018.156
    [14] 史智慧,李莹,闫璐,等. 液相剥离法制备石墨烯及在导热硅橡胶中的应用[J]. 无机材料学报,2017,32(9):955-960. doi: 10.15541/jim20160659

    SHI Z H,LI Y,YAN L,et al. Graphene:prepared by high speed shearing-assisted exfoliation and application in thermal conductive silicon[J]. Journal of Inorganic Materials,2017,32(9):955-960.) doi: 10.15541/jim20160659
    [15] 贾营坤,陈培,张青红,等. 高温热还原氧化石墨烯/聚酰亚胺复合涂层的制备及防腐蚀性能研究[J]. 无机材料学报,2017,32(12):1257-1263.

    JIA Y K,CHEN P,ZHANG Q H,et al. Thermal reduced graphene oxide/polyimide nanocomposite coating:fabrication and anticorrosive property[J]. Journal of Inorganic Materials,2017,32(12):1257-1263.)
    [16] 豆立新,龚烈航,沈健,等. 复合材料添加剂对改性PTFE的摩擦转移膜的形成和稳定作用[J]. 复合材料学报,2004,21(2):65-69. doi: 10.3321/j.issn:1000-3851.2004.02.012

    DOU L X,GONG L H,SHEN J,et al. Effect of composite additives on the forming and stability of transfer films of modified PTFEs[J]. Acta Materiae Compositae Sinica,2004,21(2):65-69.) doi: 10.3321/j.issn:1000-3851.2004.02.012
    [17] BAHADUR S. The development of transfer layers and their role in polymer tribology[J]. Wear,2000,245:92-99. doi: 10.1016/S0043-1648(00)00469-5
    [18] WANGY X,YAN F Y. Tribological properties of transfer films of PTFE-based composites[J]. Wear,2006,261:1359-1366. doi: 10.1016/j.wear.2006.03.050
    [19] 林启权,毛波,董文正,等. 二硫化钼与二硫化钨填充改性聚四氟乙烯的摩擦学性能[J]. 高分子材料与工程,2016,32(11):51-57.

    LIN Q Q,MAO B,DONG W Z,et al. Tribological behaviour of polytetrafluoroethylene composites modified with molybdenum disulfide and tungsten disulfide[J]. Polymer Materials Science and Engineering,2016,32(11):51-57.)
    [20] BAHADUR S,TABOR D. The wear of filled polytetrafluoroethylene[J]. Wear,1984,98:1-13. doi: 10.1016/0043-1648(84)90213-8
    [21] 江波. 填充型聚四氟乙烯复合材料的性能及界面研究[D]. 扬州: 扬州大学, 2017.

    JIANG B. Study on properties and interface of filled PTFE composites[D]. Yangzhou: Yangzhou University, 2017.
    [22] WANG C Y,XIAO P,ZhAO J Z,et al. Biomimetic synthesis of hydrophobic calcium carbonate nanoparticles via a carbonation route[J]. Powder Technology,2006,170(1):31-35. doi: 10.1016/j.powtec.2006.08.016
    [23] YUAN W H,GU Y J,LI L. Green synthesis of graphene/Ag nanocomposites[J]. Applied Surface Science,2012,261(1):753-758.
    [24] 王新潮,李秀娟,郭辉,等. 不同比表面积石墨烯对水性环氧富锌防腐蚀涂层性能的影响[J]. 腐蚀与防护,2019,40(12):907-912. doi: 10.11973/fsyfh-201912008

    WANG X C,LI X J,GUO H,et al. Effect of graphene with different specific surface areas on properties of water-based epoxy zinc-rich anti-corrosion coating[J]. Corrosion and Protection,2019,40(12):907-912.) doi: 10.11973/fsyfh-201912008
    [25] BHARGAVA S,MARY E M,BLANCHET T A. Wear reduction mechanisms within highly wear-resistant graphene- and other carbon-filled PTFE nanocomposites [J]. Wear,2019,444/445:203163.
    [26] BRISCOE B J,SINHA S K. Wear of polymers[J]. Engineering Tribology,2002,216(6):401-413.
    [27] 吴谦,王栋,孙瑾. 聚四氟乙烯磨擦损耗的研究[J]. 四川化工,2013,16(4):8-9. doi: 10.3969/j.issn.1672-4887.2013.04.003

    WU Q,WANG D,SUN J. Research of the fiction loss of polytetrafluoroethylene[J]. Sichuan Chemical Industry,2013,16(4):8-9.) doi: 10.3969/j.issn.1672-4887.2013.04.003
    [28] 张招柱,薛群基,刘维民,等. 金属硫化物及石墨填充PTFE复合材料的摩擦磨损性能研究[J]. 复合材料学报,1999,16(4):58-63. doi: 10.3321/j.issn:1000-3851.1999.04.012

    ZHANG Z Z,XUE Q J,LIU W M,et al. Study on friction and wear properties of metal sulfides and graphite filled PTFE composites[J]. Acta Materiae Compositae Sinica,1999,16(4):58-63.) doi: 10.3321/j.issn:1000-3851.1999.04.012
    [29] SUN J L,DU S N. Application of graphene derivatives and their nanocomposites in tribology and lubrication:a review[J]. RSC Advances,2019,9:40642-40661. doi: 10.1039/C9RA05679C
    [30] KO J H,KWON S,BYUN I S,et al. Nanotribological properties of fluorinated,hydrogenated,and oxidized graphenes[J]. Tribology Letters,2013,50:137-144. doi: 10.1007/s11249-012-0099-1
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(9)  / Tables(2)

    Get Citation
    PDF
    XML

    Article Metrics

    Article views (5109) PDF downloads(167) Cited by()
    Proportional views
    Related

    Copyright © 2015 Editorial Board of Journal of Aeronautical Materials

    京ICP备15058934号-1

    Address：P.Q.BOX 81-44,Beijing 100095,China

     E-mail：info@hkclxb.cn

    Supported by Beijing Renhe Information Technology Co. Ltd   百度统计

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return