Volume 36 Issue 2
Apr.  2016
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Article Navigation >  Journal of Aeronautical Materials  > 2016  >  36(2): 40-45
Shan WANG, Zhengtao SU, Yanfen ZHAO. Effect of Filler Systems on Properties of Fluororubber Vulcanized by Peroxide[J]. Journal of Aeronautical Materials, 2016, 36(2): 40-45. doi: 10.11868/j.issn.1005-5053.2016.2.007
Citation: Shan WANG, Zhengtao SU, Yanfen ZHAO. Effect of Filler Systems on Properties of Fluororubber Vulcanized by Peroxide[J]. Journal of Aeronautical Materials, 2016, 36(2): 40-45. 10.11868/j.issn.1005-5053.2016.2.007
shu

Effect of Filler Systems on Properties of Fluororubber Vulcanized by Peroxide

doi: 10.11868/j.issn.1005-5053.2016.2.007

  • Aviation Key Laboratory of Science and Technology on Material and Application Research for Vibration and Noise Reduction, Beijng Institute of Aeronautical Materials, Beijing 100095, China

  • Received Date: 2015-08-07
  • Rev Recd Date: 2015-12-22
  • Publish Date: 2016-04-01
    Abstract
  • The effect of nano inorganic filler systems on curability, mechanical property, thermal aging property, thermal conductivity and thermal stability of peroxide vulcanization of fluororubber was investigated. The results show that T90 of fluororubbers is delayed with the addition of different morphology of carbon nano-materials compared with BaSO4, BN and R930. The mechanical property and reinforcing efficiency of fluoroelastomer filled by CNTs, graphite and N990 are increased more than the others, when all the vulcanized rubbers possesse the same hardness. CNTs shows the best reinforcing efficiency. Inorganic filler CNTs can increase the tear strength, but it can also result in a higher compression set. Thermal aging property and compression set resistance of fluororubber filled with Graphite and N990 have better performance. Compression set of fluororubber is minimum with the addition of rutile type TiO2(R930). Graphite and BN are benefit to thermal conductivity. Fluororubber with BaSO4 possesses the highest decomposition temperature and the smallest mass loss.

     

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    • References(16)
  • [1] 曹鸿璋, 刘杰民, 张玉玺. 氟橡胶改性技术研究进展[J]. 橡胶工业,  2014, (3): 187-191. CAO H Z, LIU J M, ZHANG Y X. Progress on modification technology research of fluoroelastomers[J]. China Rubber Industry, 2014(3): 187-191.
    [2] 刘伯南. 26类氟橡胶技术[J]. 有机氟工业,  2011, (3): 59-64. LIU B N. Technology of fluoroelastomer 26[J]. Organo-Fluorine Industry, 2011(3): 59-64.
    [3] 陈青, 魏伯荣, 胡小锋. 氟橡胶的改性研究进展[J]. 特种橡胶制品,  2004, 25(2): 57-61. CHEN Q, WEI B R, HU X F. Progress on the modifying research of fluororubber[J]. Special Purpose Rubber Products, 2004, 25(2): 57-61.
    [4] 徐竹, 马俊辉, 陈军. 不同填料对246型氟橡胶性能的影响[J]. 特种橡胶制品,  2005, 26(6): 21-23. XU Z, MA J H, CHEN J. Influence of different fillers on property of fluoroelastomer 246[J]. Special Purpose Rubber Products, 2005, 26(6): 21-23.
    [5] 徐竹.填料体系对氟橡胶的性能影响极其表征.四川:四川大学,2006:17.
    [6] 崔小明. 氟橡胶的改性及应用研究进展[J]. 中国橡胶,  2015, (8): 42-45. CUI X M. Progress on the modifying and application research of fluororubber[J]. China Rubber, 2015(8): 42-45.
    [7] 方晓波, 黄承亚. 不同填料对氟橡胶性能的影响[J]. 特种橡胶制品,  2008, 29(3): 32-34. FANG X B, HUANG C Y. Influence of different fillers on the properties of fluoro rubber[J]. Special Purpose Rubber Products, 2008, 29(3): 32-34.
    [8] 陈军, 倪海鹰, 张旭刚. 填料形态及加工工艺与氟橡胶拉伸性能关系[J]. 特种橡胶制品,  2004, 25(3): 17-19. CHEN J, NI H Y, ZHANG X G. Influence of shapes of filler and processing technology on the tensile property of fluoro-rubber[J]. Special Purpose Rubber Products, 2004, 25(3): 17-19.
    [9] WANG J H, JI C T, YAN Y T. Mechanical and ceramifiable properties of silicone rubber filled with different inorganic fillers[J]. Polymer Degradation and Stability, 2015(121): 149-156.
    [10] KADER M A, LYU M Y, NAH C. A sdudy on melt processing and thermal properties of fluoroelastomer nanocomposites[J]. Composites Science and Technology, 2006, 66(10): 1431-1443.
    [11] 肖凤亮,彭兵,杨文良.氟弹性体选用手册[M].北京:化学工业出版社,2007.
    [12] 施利毅, 姚健, 于福涛. 纳米材料在高性能橡胶开发中的应用进展[J]. 中国橡胶,  2007, 23(23): 32-36. SHI L Y, YAO J, YU F T. Application progress on development of nano materials in high-performance rubber[J]. China Rubber, 2007, 23(23): 32-36.
    [13] 金文琴.新型有机杂化六方氮化硼及其高性能阻燃双马来酰亚胺树脂的研究.苏州:苏州大学,2014:27.
    [14] 秦丽丽, 王占京, 侯军. 氮化硼填充导热绝缘复合材料的研究进展[J]. 高分子材料科学与工程,  2013, 29(9): 175-178. QIN L L, WANG Z J, HOU J. Advances in insulating thermal conductive composite filled with BN[J]. Polymer Materials Science and Engineering, 2013, 29(9): 175-178.
    [15] SICHEL E K, MICLER R E, ABRAHAMS M S. Heat capacity and thermal conductivity of hexagonal pyrolytic boron nitride[J]. Physical Review:B,Condensed Matter, 1976, 13(10): 4607-4611.
    [16] 周文英, 王子君, 董丽娜. 聚合物/BN导热复合材料研究进展[J]. 合成树脂及塑料,  2015, 32(2): 80-84. ZHOU W Y, WANG Z J, DONG L N. Research progress on polymer/BN thermal conductive composites[J]. China Synthetic Resin and Plastics, 2015, 32(2): 80-84.
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